Ok, I've been gone for a while, but anyway
The Foppa mixes is not the place to go if you're new to QW teamplay - the map of choice is DM3, and the mixers will expect you to have a thorough knowledge of this map if you join a game - like where the weapons, powerups, spawn points and teleports are, the timing of items, what to do when the enemy is keeping this or that area, where to go, etc etc. Speccing is good, but make sure you watch some clan demos too, the playstyle can be very different.
A lot of high-level players are free with advice, tips and tactics - questions in #qwrookie will get answers. You can use the Quakenet
Webchat if you don't want to install an IRC client. In #qwrookie you will get op status, meaning you can employ the .qw command to find players for your mix. Something like
.qw Rookie mix at foppa3
. This can be done in-game as well
There seems to be some rookie 4on4 thing going on Sundays, I'd be there if I had the time - I love 4on4, but if I were to play Foppa mixes I would be a burden to my team. I'm no rookie, but my lack of 4on4 experience would spoil the games for the top dogs - who would have a 3on4 match, or worse. The Sunday rookie mixes sounds like a great idea. There's lots of 2on2 games going on every day, at least there used to be, and gathering four rookies for a match is a lot easier that eight. I recommend doing this if you get bored with FFA
Finally, there's some great youtube videos if you're interested in 4on4: DDKs excellent
guides. QuakePhil's uploaded some demos showing the use of
voice in QWGood luck!